Research Article
Year 2018,
Volume: 14 Issue: 3, 327 - 331, 30.09.2018
Abstract
References
- 1. Melgar, M.J, Santaeufemia, M, Garcìa, M.A, Organophosphorus pesticide residues in raw milk and infant formulas from Spanish northwest, Journal of Environmental Science and Health, Part B, 2010, 45, 595–600.
- 2. Ergonen, A.T, Salacin S, Ozdemir M.H, Pesticide use among greenhouse workers in Turkey. The Journal of Clinical Forensic Medicine, 2005, 12, 205–208.
- 3. Blair, A, Zahm, S.H, Pearce, N.E, Heineman E.F, Fraumeni J, Clues to cancer etiology from studies of farmers, Scandinavian Journal of Work, Environment and Health, 1992, 18, 209–215.
- 4. Nicolopoulou-Stamati, P, Maipas, S, Kotampasi, C, Stamatis, P, Hens, L, Chemical Pesticides and Human Health: The Urgent Need for a New Concept in Agriculture, Frontiers Public Health, 2016, 4(148), 1-8.
- 5. Sun, X.H, Song, J.R., Tan, Z.C, Di, Y.Y, Ma, H.X, Wang, M.H, Sun, L.X, Heat capacity and enthalpy of fusion of penconazole, Thermochimica Acta, 413(1-2), 261-265.
- 6. Jimenez, J.J, Bernal, J.L, del Nozal, M.J, Toribio, L, Arias, E, Analysis of pesticide residues in wine by solid-phase extraction and gas chromatography with electron capture and nitrogen–phosphorus detection, Journal of Chromatography A, 2001, 919, 147–156.
- 7. Gelsomino, A, Petrovičowȧ, B, Tiburtini, S, Magnani, E, Felici, M, Multiresidue analysis of pesticides in fruits and vegetables by gel permeation chromatography followed by gas chromatography with electron-capture and mass spectrometric detection, Journal of Chromatography A, 1997, 782, 105-122.
- 8. Oliva, J, Navarro, S, Barba, A, Navarro G, Determination of chlorpyrifos, penconazole, fenarimol, vinclozolin and metalaxyl in grapes, must and wine by on-line microextraction and gas chromatography, Journal of Chromatography A, 1999, 833, 43–51.
- 9. Navarro, S, Barba, A, Navarro, G, Vela, N, Oliva, J, Multiresidue method for the rapid determination – in grape, must and wine–of fungicides frequently used on vineyards, Journal of Chromatography A, 2000, 882, 221–229.
- 10. Arrebola, F.J, Martínez Vidal, J.L, Mateu-Sánchez, M, Álvarez-Castellón, F.J, Determination of 81 multiclass pesticides in fresh foodstuffs by a single injection analysis using gas chromatography–chemical ionization and electron ionization tandem mass spectrometry, Analytica Chimica Acta, 2003, 484, 167–180.
- 11. Pan, H.J, Ho, W.H, Determination of fungicides in water using liquid phase microextraction and gas chromatography with electron capture detection, Analytica Chimica Acta, 2004, 527, 61–67.
- 12. Hirahara, Y, Tsumura, Y, Nakamura, Y, Tonogai, Y, Shibata, T, Analysis of Phenothrin and Its Metabolite 3-Phenoxybenzoic Acid (PBA) in Agricultural Products by GC and lon-Trap GC/MS, Journal of Food Protection, 1997, 60(3), 305-309.
- 13. Sakaue, S, Kitajima, M, Doi, T, High Performance Liquid Chromatographic Determination of d-Phenothrin (Sumithrin®) in Shampoo, Agricultural and Biological Chemistry, 1985, 49(9), 2787-2789.
- 14. Pacioni, N.L, Veglia, A.V, Determination of poorly fluorescent carbamate pesticides in water, bendiocarb and promecarb, using cyclodextrin nanocavities and related media, Analytica Chimica Acta, 2007, 583, 63–71.
- 15. Sicbaldi, F, Sarra, A, Copeta, G.L, Diatomaceous earth-assisted extraction for the multiresidue determination of pesticides, Journal of Chromatography A, 1997, 765, 23-30.
- 16. Millȧn, S, Sampedro, M.C, Unceta, N, Goicolea, M.A, Rodriguez, E, Barrio, R.J, Coupling solid-phase microextraction and high-performance liquid chromatography for direct and sensitive determination of halogenated fungicides in wine, Journal of Chromatography A, 2003, 995, 135–142.
- 17. Ferrer, I, Thurman, E.M, Liquid chromatography time-of-flight mass spectrometry:principles, tools, and application for accurate mass analysis, John Wiley & Sons, Inc, 2009, 280 p., pp. 251.
- 18. Pang, G.F, Analytical Methods for Food Safety by Mass Spectrometry: Volume I Pesticides, Academic Press, 2018, 880 p., pp. 43.
- 19. Lunn, G, HPLC Methods for Recently Approved Pharmaceuticals, John Wiley & Sons, Inc., 2005, pp. 26.
- 20. Loper, B.L, Anderson, K.A, Determination of pyrethrin and pyrethroid pesticides in urine and water matrixes by liquid chromatography with diode array detection, Journal of AOAC International, 2003, 86(6), 1236-1240.
Analytical Method Development and Validation of Phenothrin, Promecarb and Penconazole in Tobacco using Liquid Extraction and Gas Chromatography
Abstract
A sensitive method for the determination of
phenothrin, promecarb and
penconazole residues in tobacco has been developed. Several solvents such as,
hexane, ethyl acetate and dichloromethane were tested in order to minimize
agricultural products residue. In the study, the best recovery was achieved
with dichloromethane. Pesticides residues are extracted from the samples with
dichloromethane. Additional clean-up steps are not required for tobacco
matrices. Determination and quantification of phenothrin, promecarb and penconazole are
performed by gas chromatography-flame ionization detector (GC/FID) and gas
chromatography-nitrogen/phosphorus (GC/NPD). The method has been validated for
tobacco matrices. Under the optimum
conditions, phenothrin R2 value 0.999, promecarb
R2 value 0.999, and penconazole R2 value 0.999. Limits of
determination were 0.008 µg mL-1 for phenothrin, 0.011 µg mL-1 for
penconazole and 0.007 µg mL-1 for promecarb. The standard deviations (SDs) levels were in the range
0.01-0.20. Recoveries of phenothrin, promecarb
and penconazole from tobacco were found to be higher than 85%. Under this developed
method, the concentrations of phenothrin, promecarb and penconazole in the 10 tobacco samples were below the
LOD values.
phenothrin, promecarb and
penconazole residues in tobacco has been developed. Several solvents such as,
hexane, ethyl acetate and dichloromethane were tested in order to minimize
agricultural products residue. In the study, the best recovery was achieved
with dichloromethane. Pesticides residues are extracted from the samples with
dichloromethane. Additional clean-up steps are not required for tobacco
matrices. Determination and quantification of phenothrin, promecarb and penconazole are
performed by gas chromatography-flame ionization detector (GC/FID) and gas
chromatography-nitrogen/phosphorus (GC/NPD). The method has been validated for
tobacco matrices. Under the optimum
conditions, phenothrin R2 value 0.999, promecarb
R2 value 0.999, and penconazole R2 value 0.999. Limits of
determination were 0.008 µg mL-1 for phenothrin, 0.011 µg mL-1 for
penconazole and 0.007 µg mL-1 for promecarb. The standard deviations (SDs) levels were in the range
0.01-0.20. Recoveries of phenothrin, promecarb
and penconazole from tobacco were found to be higher than 85%. Under this developed
method, the concentrations of phenothrin, promecarb and penconazole in the 10 tobacco samples were below the
LOD values.
Keywords
Tobacco GC phenothrin promecarb penconazole liquid extraction
References
- 1. Melgar, M.J, Santaeufemia, M, Garcìa, M.A, Organophosphorus pesticide residues in raw milk and infant formulas from Spanish northwest, Journal of Environmental Science and Health, Part B, 2010, 45, 595–600.
- 2. Ergonen, A.T, Salacin S, Ozdemir M.H, Pesticide use among greenhouse workers in Turkey. The Journal of Clinical Forensic Medicine, 2005, 12, 205–208.
- 3. Blair, A, Zahm, S.H, Pearce, N.E, Heineman E.F, Fraumeni J, Clues to cancer etiology from studies of farmers, Scandinavian Journal of Work, Environment and Health, 1992, 18, 209–215.
- 4. Nicolopoulou-Stamati, P, Maipas, S, Kotampasi, C, Stamatis, P, Hens, L, Chemical Pesticides and Human Health: The Urgent Need for a New Concept in Agriculture, Frontiers Public Health, 2016, 4(148), 1-8.
- 5. Sun, X.H, Song, J.R., Tan, Z.C, Di, Y.Y, Ma, H.X, Wang, M.H, Sun, L.X, Heat capacity and enthalpy of fusion of penconazole, Thermochimica Acta, 413(1-2), 261-265.
- 6. Jimenez, J.J, Bernal, J.L, del Nozal, M.J, Toribio, L, Arias, E, Analysis of pesticide residues in wine by solid-phase extraction and gas chromatography with electron capture and nitrogen–phosphorus detection, Journal of Chromatography A, 2001, 919, 147–156.
- 7. Gelsomino, A, Petrovičowȧ, B, Tiburtini, S, Magnani, E, Felici, M, Multiresidue analysis of pesticides in fruits and vegetables by gel permeation chromatography followed by gas chromatography with electron-capture and mass spectrometric detection, Journal of Chromatography A, 1997, 782, 105-122.
- 8. Oliva, J, Navarro, S, Barba, A, Navarro G, Determination of chlorpyrifos, penconazole, fenarimol, vinclozolin and metalaxyl in grapes, must and wine by on-line microextraction and gas chromatography, Journal of Chromatography A, 1999, 833, 43–51.
- 9. Navarro, S, Barba, A, Navarro, G, Vela, N, Oliva, J, Multiresidue method for the rapid determination – in grape, must and wine–of fungicides frequently used on vineyards, Journal of Chromatography A, 2000, 882, 221–229.
- 10. Arrebola, F.J, Martínez Vidal, J.L, Mateu-Sánchez, M, Álvarez-Castellón, F.J, Determination of 81 multiclass pesticides in fresh foodstuffs by a single injection analysis using gas chromatography–chemical ionization and electron ionization tandem mass spectrometry, Analytica Chimica Acta, 2003, 484, 167–180.
- 11. Pan, H.J, Ho, W.H, Determination of fungicides in water using liquid phase microextraction and gas chromatography with electron capture detection, Analytica Chimica Acta, 2004, 527, 61–67.
- 12. Hirahara, Y, Tsumura, Y, Nakamura, Y, Tonogai, Y, Shibata, T, Analysis of Phenothrin and Its Metabolite 3-Phenoxybenzoic Acid (PBA) in Agricultural Products by GC and lon-Trap GC/MS, Journal of Food Protection, 1997, 60(3), 305-309.
- 13. Sakaue, S, Kitajima, M, Doi, T, High Performance Liquid Chromatographic Determination of d-Phenothrin (Sumithrin®) in Shampoo, Agricultural and Biological Chemistry, 1985, 49(9), 2787-2789.
- 14. Pacioni, N.L, Veglia, A.V, Determination of poorly fluorescent carbamate pesticides in water, bendiocarb and promecarb, using cyclodextrin nanocavities and related media, Analytica Chimica Acta, 2007, 583, 63–71.
- 15. Sicbaldi, F, Sarra, A, Copeta, G.L, Diatomaceous earth-assisted extraction for the multiresidue determination of pesticides, Journal of Chromatography A, 1997, 765, 23-30.
- 16. Millȧn, S, Sampedro, M.C, Unceta, N, Goicolea, M.A, Rodriguez, E, Barrio, R.J, Coupling solid-phase microextraction and high-performance liquid chromatography for direct and sensitive determination of halogenated fungicides in wine, Journal of Chromatography A, 2003, 995, 135–142.
- 17. Ferrer, I, Thurman, E.M, Liquid chromatography time-of-flight mass spectrometry:principles, tools, and application for accurate mass analysis, John Wiley & Sons, Inc, 2009, 280 p., pp. 251.
- 18. Pang, G.F, Analytical Methods for Food Safety by Mass Spectrometry: Volume I Pesticides, Academic Press, 2018, 880 p., pp. 43.
- 19. Lunn, G, HPLC Methods for Recently Approved Pharmaceuticals, John Wiley & Sons, Inc., 2005, pp. 26.
- 20. Loper, B.L, Anderson, K.A, Determination of pyrethrin and pyrethroid pesticides in urine and water matrixes by liquid chromatography with diode array detection, Journal of AOAC International, 2003, 86(6), 1236-1240.
There are 20 citations in total.
Details
| Primary Language | English |
|---|---|
| Subjects | Engineering |
| Journal Section | Articles |
| Authors | |
| Publication Date | September 30, 2018 |
| Published in Issue | Year 2018 Volume: 14 Issue: 3 |