Research Article
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Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions

Year 2023, Volume: 7 Issue: 4, 403 - 409, 31.12.2023

Sertaç Coşman

https://doi.org/10.30939/ijastech..1397506
Cited By: 1

Abstract

In this study, the influences of Benzoylthiourea Derivative Fuel N-(2-amino-5-bromo-1,dihydropyridine-1-yl)carbonothioyl)-2-chlorobenzamide as an additive into gas-oline were researched on engine performance and exhaust emissions. For this reason, a single-cylinder four stroke gasoline engine was run at wide open throttle, and 2400, 2800, 3200, 3600 and 4000 rpm engine speeds. The changes of engine torque, power output, specific fuel consumption, thermal efficiency, CO, CO2 and HC emissions were experi-mentally investigated.

Keywords

Benzoylthiourea Gasoline Exhaust Emissions Engine Performance Internal Combustion Engine

Thanks

The author thanks to Prof. Dr. Fatih Mehmet Emen who is researcher at Burdur Mehmet Akif Ersoy University, Faculty of Arts and Sciences in the Department of Chemistry for his great efforts and contributions to the study.

References

  • [1] Solmaz, H., Calam, A., Yılmaz, E., Şahin, F., Ardebili, S. M. S., & Aksoy, F. Evaluation of MWCNT as fuel additive to diesel–biodiesel blend in a direct injection diesel engine. Biofuels. 2023;14(2), 147-156.
  • [2] Daud, S., Hamidi, M. A., & Mamat, R. A review of fuel addi-tives' effects and predictions on internal combustion engine performance and emissions. AIMS Energy. 2022;10(1), 1-22.
  • [3] Siddartha, G. N. V., Ramakrishna, C. S., Kujur, P. K., Rao, Y. A., Dalela, N., Yadav, A. S., & Sharma, A. Effect of fuel addi-tives on internal combustion engine performance and emissions. Materials Today: Proceedings 63. 2022;A9-A14.
  • [4] Solmaz, H., Ardebili, S. M. S., Calam, A., Yılmaz, E., & İpci, D., Prediction of performance and exhaust emissions of a CI engine fueled with multi-wall carbon nanotube doped bio-diesel-diesel blends using response surface method. Energy, 2021; 227, 120518.
  • [5] Alli, A. K., & Kotha, M. M. Significance of fuel additives on the performance and emission characteristics of diesel engine with biodiesel fuel: a review. International Journal of Ambient Energy. 2023;1-15.
  • [6] Srinivas Rao, T., Jakeer Hussain, S., Dhana Raju, V., Venu, H., Subramani, L. Experimental assessment of various fuel addi-tives on the performance and emission characteristics of the spark ignition engine. International Journal of Ambient Energy. 2022;43(1), 1333-1338.
  • [7] Kocakulak, T., Uyumaz A., Arabacı E., Dağoğlu Y., Çamoğlu C. Experimental Investigation of the Effects of Gasoline-Methyl Ethyl Ketone Fuel Blends on Engine Performance and Exhaust Emissions. Journal of Materials and Mecathronics:A. 2023;4(2), 397-408.
  • [8] Bayrakçeken, H., Yavuz, H., Arslan, T.A. Effect of Clutch Distances on Fuel Consumption Under Actual Operating Condi-tions. Engineering Perspective. 2023;3(4), 63-67.
  • [9] Kilic, A. Charging Techniques, Infrastructure, and Their Influ-ences. Engineering Perspective. 2023;3(4), 68-74.
  • [10] Plutín, A. M., Alvarez, A., Mocelo, R., Ramos, R., Cas-tellano, E. E., Da Silva, M. M., Vegas, L. C., Pavan, F. R., Ba-tista, A.A. Anti-Mycobacterium tuberculosis activity of plati-num (II)/N, N-disubstituted-N′-acyl thiourea complexes. Inor-ganic Chemistry Communications. 2016;63, 74-80.
  • [11] Çelik, H., Karipcin, F. Çok dişli tiyoüre türevi ligandların ve bunların metal komplekslerinin sentezi ve karakterizasyonu, Master's thesis, Nevşehir Hacı Bektaş Veli Üniversitesi, 2016.
  • [12] Karipcin, F. Bazı soy metallerinin N, N-dialkilin-N-benzoil tiyoüre türevleri ile şelatlarının sentezlenmesi, Master's thesis, Fen Bilimleri Enstitüsü, 1995.
  • [13] Mukiza, J., Braband, H., Bolliger, R., Blacque, O., Al-berto, R., Nkurunziza, J. B. A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re (CO) 3]+ core. Inorganica Chimica Acta. 2021;516, 120116.
  • [14] Binzet, G., Zeybek, B., Kılıç, E., Külcü, N., Arslan, H. Determination of the ionization constants of some benzoyl thi-ourea derivatives in dioxane-water mixture. Journal of Chemis-try, 2013.
  • [15] Yesilkaynak, T., Binzet, G., Emen, F. M., Flörke, U., Külcü, N., Arslan, H. Theoretical and experimental studies on N-(6-methylpyridin-2-yl-carbamothioyl) biphenyl-4-carboxamide. European Journal of Chemistry, 2010;1(1), 1-5. [16] Arslan, H., Külcü, N., Flörke, U. Synthesis and charac-terization of copper (II), nickel (II) and cobalt (II) complexes with novel thiourea derivatives. Transition Metal Chemistry. 2003;28, 816-819.
  • [17] Poyraz, S., Döndaş, H. A., Sansano, J. M., Belveren, S., Yamali, C., Ülger, M., Döndaş, N. Y., Sağlık, B. N., Pask, C. M. N-Benzoylthiourea-pyrrolidine carboxylic acid derivatives bearing an imidazole moiety: Synthesis, characterization, crys-tal structure, in vitro ChEs inhibition, and antituberculosis, anti-bacterial, antifungal studies. Journal of Molecular Structure. 2023;1273, 134303.
  • [18] Kadhem, N. A., Jwaid, A. H., Atia, A. J. K., Synthesis of new azo-heterocyclic compounds derived from benzoylthiou-rea, evaluation of their biological activity and lethal dose. Bio-chemical & Cellular Archives. 2021;21.
  • [19] Gumus, I., Solmaz, U., Celik, O., Binzet, G., Balcı, G. K., & Arslan, H. Synthesis, characterization and crystal structure of cis-bis [4-fluoro-N-(diethylcarbamothioyl) benzamido-κ2O, S] platinum (II). European Journal of Chemistry. 2015;6(3), 237-241.
  • [20] Solmaz, U., Gumus, I., Yilmaz, M. K., Ince, S., Arslan, H. Palladium complexes derived from benzoylthiourea ligands: Synthesis, crystal structure, and catalytic application in Suzuki C–C coupling reactions. Applied Organometallic Chemistry. 2021;35(10), e6348.
  • [21] Solmaz, U., Arslan, H. Spectral, crystallographic, theo-retical, and catalytic activity studies of the PdII complexes in different coordination modes of benzoylthiourea ligand. Jour-nal of Molecular Structure. 2022;1269, 133839.
  • [22] Khan, U. A., Badshah, A., Tahir, M. N., & Khan, E. Gold (I), silver (I) and copper (I) complexes of 2, 4, 6-trimethylphenyl-3-benzoylthiourea; synthesis and biological applications. Polyhedron. 2020;181, 114485.
  • [23] Limbeck, A., Puls, C., & Handler, M. Platinum and pal-ladium emissions from on-road vehicles in the Kaisermühlen Tunnel (Vienna, Austria). Environmental science & technology. 2007;41(14), 4938-4945.
  • [24] Keskin, A., Ocakoglu, K., Resitoglu, I. A., Avsar, G., Emen, F. M., & Buldum, B. Using Pd (II) and Ni (II) complexes with N, N-dimethyl-N′-2-chlorobenzoylthiourea ligand as fuel additives in diesel engine. Fuel. 2015;162, 202-206.
  • [25] Keskin, A., Yaşar, A., Yıldızhan, Ş., Uludamar, E., Emen, F. M., Külcü, N. Evaluation of diesel fuel-biodiesel blends with palladium and acetylferrocene based additives in a diesel engine. Fuel. 2018;216, 349-355.
  • [26] Yeşilkaynak, T., Özkömeç, F. N., Çeşme, M., Demirdöğen, R. E., Kutlu, E., Kutlu, H. M., Emen, F. M. Syn-thesis of new thiourea derivatives and metal complexes: Ther-mal behavior, biological evaluation, in silico ADMET profiling and molecular docking studies. Journal of Molecular Structure. 2022;1269, 133758.
  • [27] Calam, A., Solmaz, H., Uyumaz, A., Polat, S., Yilmaz, E., İçingür, Y. Investigation of usability of the fusel oil in a single cylinder spark ignition engine. Journal of the energy institute. 2015;88(3), 258-265.
  • [28] Elfasakhany, A. Performance and emissions analysis on using acetone–gasoline fuel blends in spark-ignition en-gine. Engineering Science and Technology, an International Journal. 2016;19(3), 1224-1232.
  • [29] Uyumaz, A. Experimental Research With Diethyl Ether on Engine Performance and Emissions in a Spark Ignition En-gine. International Journal of Automotive Science and Tech-nology. 2023;7(3), 167-174.
  • [30] Górski, K., Smigins, R., & Longwic, R. Research on physico-chemical properties of diethyl ether/linseed oil blends for the use as fuel in diesel engines. Energies. 2020;13(24), 6564.
  • [31] Holman, J.P., Experimental Methods for Engineers, McGraw Hill, Newyork, 2012.
  • [32] Mofat, R.J.: Using uncertainty analysis in the planning of an experiment. J Fluids Eng. 1985;107(2), 173-178.
  • [33] Kumar D.S., Murugesan S., Experimental Investigation on Impact of Diethyl Ether Additives with Cashew Nut Shell Liquid Biodiesel Blends on Performance Characteristics of En-gine Operating at Optimum Conditions. Emission Control Sci-ence and Technology. 2023; 9:66-75.
  • [34]Heywood, J. B. Internal combustion engine fundamentals. McGrawHill Publishing Company; New York, 1988.

Year 2023, Volume: 7 Issue: 4, 403 - 409, 31.12.2023

Sertaç Coşman

https://doi.org/10.30939/ijastech..1397506
Cited By: 1

Abstract

References

  • [1] Solmaz, H., Calam, A., Yılmaz, E., Şahin, F., Ardebili, S. M. S., & Aksoy, F. Evaluation of MWCNT as fuel additive to diesel–biodiesel blend in a direct injection diesel engine. Biofuels. 2023;14(2), 147-156.
  • [2] Daud, S., Hamidi, M. A., & Mamat, R. A review of fuel addi-tives' effects and predictions on internal combustion engine performance and emissions. AIMS Energy. 2022;10(1), 1-22.
  • [3] Siddartha, G. N. V., Ramakrishna, C. S., Kujur, P. K., Rao, Y. A., Dalela, N., Yadav, A. S., & Sharma, A. Effect of fuel addi-tives on internal combustion engine performance and emissions. Materials Today: Proceedings 63. 2022;A9-A14.
  • [4] Solmaz, H., Ardebili, S. M. S., Calam, A., Yılmaz, E., & İpci, D., Prediction of performance and exhaust emissions of a CI engine fueled with multi-wall carbon nanotube doped bio-diesel-diesel blends using response surface method. Energy, 2021; 227, 120518.
  • [5] Alli, A. K., & Kotha, M. M. Significance of fuel additives on the performance and emission characteristics of diesel engine with biodiesel fuel: a review. International Journal of Ambient Energy. 2023;1-15.
  • [6] Srinivas Rao, T., Jakeer Hussain, S., Dhana Raju, V., Venu, H., Subramani, L. Experimental assessment of various fuel addi-tives on the performance and emission characteristics of the spark ignition engine. International Journal of Ambient Energy. 2022;43(1), 1333-1338.
  • [7] Kocakulak, T., Uyumaz A., Arabacı E., Dağoğlu Y., Çamoğlu C. Experimental Investigation of the Effects of Gasoline-Methyl Ethyl Ketone Fuel Blends on Engine Performance and Exhaust Emissions. Journal of Materials and Mecathronics:A. 2023;4(2), 397-408.
  • [8] Bayrakçeken, H., Yavuz, H., Arslan, T.A. Effect of Clutch Distances on Fuel Consumption Under Actual Operating Condi-tions. Engineering Perspective. 2023;3(4), 63-67.
  • [9] Kilic, A. Charging Techniques, Infrastructure, and Their Influ-ences. Engineering Perspective. 2023;3(4), 68-74.
  • [10] Plutín, A. M., Alvarez, A., Mocelo, R., Ramos, R., Cas-tellano, E. E., Da Silva, M. M., Vegas, L. C., Pavan, F. R., Ba-tista, A.A. Anti-Mycobacterium tuberculosis activity of plati-num (II)/N, N-disubstituted-N′-acyl thiourea complexes. Inor-ganic Chemistry Communications. 2016;63, 74-80.
  • [11] Çelik, H., Karipcin, F. Çok dişli tiyoüre türevi ligandların ve bunların metal komplekslerinin sentezi ve karakterizasyonu, Master's thesis, Nevşehir Hacı Bektaş Veli Üniversitesi, 2016.
  • [12] Karipcin, F. Bazı soy metallerinin N, N-dialkilin-N-benzoil tiyoüre türevleri ile şelatlarının sentezlenmesi, Master's thesis, Fen Bilimleri Enstitüsü, 1995.
  • [13] Mukiza, J., Braband, H., Bolliger, R., Blacque, O., Al-berto, R., Nkurunziza, J. B. A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re (CO) 3]+ core. Inorganica Chimica Acta. 2021;516, 120116.
  • [14] Binzet, G., Zeybek, B., Kılıç, E., Külcü, N., Arslan, H. Determination of the ionization constants of some benzoyl thi-ourea derivatives in dioxane-water mixture. Journal of Chemis-try, 2013.
  • [15] Yesilkaynak, T., Binzet, G., Emen, F. M., Flörke, U., Külcü, N., Arslan, H. Theoretical and experimental studies on N-(6-methylpyridin-2-yl-carbamothioyl) biphenyl-4-carboxamide. European Journal of Chemistry, 2010;1(1), 1-5. [16] Arslan, H., Külcü, N., Flörke, U. Synthesis and charac-terization of copper (II), nickel (II) and cobalt (II) complexes with novel thiourea derivatives. Transition Metal Chemistry. 2003;28, 816-819.
  • [17] Poyraz, S., Döndaş, H. A., Sansano, J. M., Belveren, S., Yamali, C., Ülger, M., Döndaş, N. Y., Sağlık, B. N., Pask, C. M. N-Benzoylthiourea-pyrrolidine carboxylic acid derivatives bearing an imidazole moiety: Synthesis, characterization, crys-tal structure, in vitro ChEs inhibition, and antituberculosis, anti-bacterial, antifungal studies. Journal of Molecular Structure. 2023;1273, 134303.
  • [18] Kadhem, N. A., Jwaid, A. H., Atia, A. J. K., Synthesis of new azo-heterocyclic compounds derived from benzoylthiou-rea, evaluation of their biological activity and lethal dose. Bio-chemical & Cellular Archives. 2021;21.
  • [19] Gumus, I., Solmaz, U., Celik, O., Binzet, G., Balcı, G. K., & Arslan, H. Synthesis, characterization and crystal structure of cis-bis [4-fluoro-N-(diethylcarbamothioyl) benzamido-κ2O, S] platinum (II). European Journal of Chemistry. 2015;6(3), 237-241.
  • [20] Solmaz, U., Gumus, I., Yilmaz, M. K., Ince, S., Arslan, H. Palladium complexes derived from benzoylthiourea ligands: Synthesis, crystal structure, and catalytic application in Suzuki C–C coupling reactions. Applied Organometallic Chemistry. 2021;35(10), e6348.
  • [21] Solmaz, U., Arslan, H. Spectral, crystallographic, theo-retical, and catalytic activity studies of the PdII complexes in different coordination modes of benzoylthiourea ligand. Jour-nal of Molecular Structure. 2022;1269, 133839.
  • [22] Khan, U. A., Badshah, A., Tahir, M. N., & Khan, E. Gold (I), silver (I) and copper (I) complexes of 2, 4, 6-trimethylphenyl-3-benzoylthiourea; synthesis and biological applications. Polyhedron. 2020;181, 114485.
  • [23] Limbeck, A., Puls, C., & Handler, M. Platinum and pal-ladium emissions from on-road vehicles in the Kaisermühlen Tunnel (Vienna, Austria). Environmental science & technology. 2007;41(14), 4938-4945.
  • [24] Keskin, A., Ocakoglu, K., Resitoglu, I. A., Avsar, G., Emen, F. M., & Buldum, B. Using Pd (II) and Ni (II) complexes with N, N-dimethyl-N′-2-chlorobenzoylthiourea ligand as fuel additives in diesel engine. Fuel. 2015;162, 202-206.
  • [25] Keskin, A., Yaşar, A., Yıldızhan, Ş., Uludamar, E., Emen, F. M., Külcü, N. Evaluation of diesel fuel-biodiesel blends with palladium and acetylferrocene based additives in a diesel engine. Fuel. 2018;216, 349-355.
  • [26] Yeşilkaynak, T., Özkömeç, F. N., Çeşme, M., Demirdöğen, R. E., Kutlu, E., Kutlu, H. M., Emen, F. M. Syn-thesis of new thiourea derivatives and metal complexes: Ther-mal behavior, biological evaluation, in silico ADMET profiling and molecular docking studies. Journal of Molecular Structure. 2022;1269, 133758.
  • [27] Calam, A., Solmaz, H., Uyumaz, A., Polat, S., Yilmaz, E., İçingür, Y. Investigation of usability of the fusel oil in a single cylinder spark ignition engine. Journal of the energy institute. 2015;88(3), 258-265.
  • [28] Elfasakhany, A. Performance and emissions analysis on using acetone–gasoline fuel blends in spark-ignition en-gine. Engineering Science and Technology, an International Journal. 2016;19(3), 1224-1232.
  • [29] Uyumaz, A. Experimental Research With Diethyl Ether on Engine Performance and Emissions in a Spark Ignition En-gine. International Journal of Automotive Science and Tech-nology. 2023;7(3), 167-174.
  • [30] Górski, K., Smigins, R., & Longwic, R. Research on physico-chemical properties of diethyl ether/linseed oil blends for the use as fuel in diesel engines. Energies. 2020;13(24), 6564.
  • [31] Holman, J.P., Experimental Methods for Engineers, McGraw Hill, Newyork, 2012.
  • [32] Mofat, R.J.: Using uncertainty analysis in the planning of an experiment. J Fluids Eng. 1985;107(2), 173-178.
  • [33] Kumar D.S., Murugesan S., Experimental Investigation on Impact of Diethyl Ether Additives with Cashew Nut Shell Liquid Biodiesel Blends on Performance Characteristics of En-gine Operating at Optimum Conditions. Emission Control Sci-ence and Technology. 2023; 9:66-75.
  • [34]Heywood, J. B. Internal combustion engine fundamentals. McGrawHill Publishing Company; New York, 1988.
There are 33 citations in total.

Details

Primary Language English
Subjects Internal Combustion Engines
Journal Section Research Articles
Authors

Sertaç Coşman 0009-0005-9360-216X

Publication Date December 31, 2023
Submission Date November 28, 2023
Acceptance Date December 30, 2023
Published in Issue Year 2023 Volume: 7 Issue: 4

Cite

APA Coşman, S. (2023). Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions. International Journal of Automotive Science And Technology, 7(4), 403-409. https://doi.org/10.30939/ijastech..1397506
AMA Coşman S. Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions. ijastech. December 2023;7(4):403-409. doi:10.30939/ijastech.1397506
Chicago Coşman, Sertaç. “Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions”. International Journal of Automotive Science And Technology 7, no. 4 (December 2023): 403-9. https://doi.org/10.30939/ijastech. 1397506.
EndNote Coşman S (December 1, 2023) Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions. International Journal of Automotive Science And Technology 7 4 403–409.
IEEE S. Coşman, “Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions”, ijastech, vol. 7, no. 4, pp. 403–409, 2023, doi: 10.30939/ijastech..1397506.
ISNAD Coşman, Sertaç. “Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions”. International Journal of Automotive Science And Technology 7/4 (December 2023), 403-409. https://doi.org/10.30939/ijastech. 1397506.
JAMA Coşman S. Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions. ijastech. 2023;7:403–409.
MLA Coşman, Sertaç. “Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions”. International Journal of Automotive Science And Technology, vol. 7, no. 4, 2023, pp. 403-9, doi:10.30939/ijastech. 1397506.
Vancouver Coşman S. Experimental Research of the Effects of Benzoylthiourea Derivative Fuel and Gasoline Mixtures on Engine Performance and Emissions. ijastech. 2023;7(4):403-9.

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